Tri-μ-chlorido-bis[(η6-hexamethylbenzene)ruthenium(II)] tetrachloridoferrate(III)
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منابع مشابه
Poly[bis(1-carbamoylguanidinium) [tri-μ-chlorido-dichloridobismuthate(III)]]
The structure of the title organic-inorganic hybrid compound, {(C(2)H(7)N(4)O)(2)[BiCl(5)]}(n), consists of corrugated chains parallel to [100] of corner-joined [BiCl(6)] octa-hedra, separated by layers of organic 1-carbamoylguanidinum cations. The crystal cohesion is achieved by N-H⋯O and N-H⋯Cl hydrogen bonds, which link the organic and inorganic parts of the structure.
متن کاملTri-μ-chlorido-bis[(η6-hexamethylbenzene)ruthenium(II)] tetrachloridoferrate(III)
The mol-ecular geometry of the complex cation in the title structure, [(μ-Cl)(3){Ru(II)(η(6)-C(6)Me(6))}(2)][Fe(III)Cl(4)], compares very well with that reported earlier for the corresponding PF(6) (-) salt [Pandey et al. (1999 ▶). J. Organomet. Chem.592, 278-282]. The [FeCl(4)](-) counter ion has a rather regular tetra-hedral geometry with Fe-Cl distances and Cl-Fe-Cl angles in the range 2.189...
متن کاملPoly[1-ethyl-3-methylimidazolium [tri-μ-chlorido-chromate(II)]]
The title compound, {(C(6)H(11)N(2))[CrCl(3)]}(n), was generated via mixing of the ionic liquid 1-ethyl-3-methyl-imidazolium chloride with CrCl(2) in ethanol. Crystals were obtained by a diffusion method. In the crystal structure, the anion forms one-dimensional chains of chloride-bridged Jahn-Teller distorted chromium(II) centers extending along the [100] direction. The imidazolium cations are...
متن کاملTri-μ-chlorido-bis[(η5-pentamethylcyclopentadienyl)rhodium(III)] hexafluoridophosphate from synchrotron radiation
In the title complex salt, [{(η(5)-C5Me5)Rh}2(μ-Cl)3]PF6, the dinuclear, single-charged cation is formed by the cojoining of two classic (η(5)-C5Me5)RhCl3 'piano-stool' units by bridging of the three choride ligand 'legs'. The crystal structure shows several close H⋯F contacts between the hexa-fluorido-phosphate counter-ions and the C5Me5 ligands.
متن کاملDi-μ-chlorido-bis[chlorido(dimethoxyphenylphosphine)palladium(II)]
The title compound, [Pd(2)Cl(4)(C(8)H(11)O(2)P)(2)], is binuclear and disposed about a crystallographic centre of symmetry with a Pd⋯Pd distance of 3.4662 (17) Å. It has a similar geometry to that observed in the triphenyl-phosphite and triphenyl-phosphine analogues. The Pd-P bond length is ca 0.04 Å shorter than those in mononuclear PdCl(2)(P(OMe)(2)Ph)(2), possibly due to the lower trans-infl...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2011
ISSN: 1600-5368
DOI: 10.1107/s160053681103621x